Passivation condition of carbon steel in bentonite/sand mixture

Taniguchi, Naoki; Kawakami, Susumu; *

JNC TN8400 2001-025, 27 Pages, 2002/03

JNC-TN8400-2001-025.pdf:1.16MB

It is essential to understand the corrosion type of carbon steel under the repository conditions for the lifetime assessment of carbon steel overpack used for geological isolation of high-level radioactive waste. According to the previous study, carbon steel is hard to passivate in buffer material assuming a chemical condition range of groundwater in Japan. However, concrete support will be constructed around the overpack in the case of repository in the soft rock system and groundwater having a higher pH may infiltrate to buffer material. There is a possibility that the corrosion type of carbon steel will be influenced by the rise of the pH in groundwater. In this study, anodic polarization experiments were performed to understand the passivation condition of carbon steel in buffer material saturated with water contacted with concrete. An ordinary concrete and a low-alkalinity concrete were used in the experiment. The results of the experiments showed that the carbon steel can passivate under the condition that water having pH 13 infiltrate to the buffer material assuming present property of buffer material. If the low-alkalinity concrete is selected as the support material, passivation can not occur on carbon steel overpack. The effect of the factors of buffer material such as dry density and mixing ratio of sand on the passivation of carbon steel was also studied. The results of the study showed that the present property of buffer material is enough to prevent passivation of carbon steel.

Study on cathodic reaction control efficiency by low alloy steels

Akashi, Masatsune*; Fukaya, Yuichi*; Asano, Hidekazu*

JNC TJ8400 2000-014, 22 Pages, 2000/02

JNC-TJ8400-2000-014.pdf:0.75MB

Difference of hydrogen generation phenomena on the surface of the Steels were not observed between carbon steel, atmospheric corrosion resisting steel and 5%-Ni steel. Rust layer was formed on these three-type of steels by steam oxidation method. And the chemical composition of the rust for the steels were basically two(2) layers structure for the previous two steels as hematite(FeO) based for the outer layer and magnetite(FeO) based for the inner layer. And for the last steel, it had three(3) layer in the rust as hematite(FeO) based for the outer layer, magnetite(FeO) based for the intermediate layer and Ni based layer for the inner layer. These steels showed mostly same Tafel gradient in their cathodic polarization curves compare with that for no rust specimens. However, the exchange current density which reaction is assumed as a hydrogen generation reaction was largely increased. The cathodic reaction for each steels whose surface is covered by magnetite layer might be accelerated, then the corrosion rate was considered as accelerated, too.

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PNC TJ1560 94-001, 78 Pages, 1994/03

PNC-TJ1560-94-001.pdf:2.14MB

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PNC TJ1150 92-003, 136 Pages, 1992/02

PNC-TJ1150-92-003.pdf:2.57MB

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Inhibition of self-passivation of SUS304 stainless steel in tritiated water solution of sulfuric acid

Oyaizu, Makoto; Hayashi, Takumi

no journal, , 

The corrosion behavior of SUS304 stainless steel and tritium effects of tritiated water on it were studied by means of electrochemical techniques. As the results, the self-passivation of SUS304 stainless steel in 1N sulfuric acid solution by dissolved oxygen was inhibited in tritiated water solution. It was also indicated that the self-passivation inhibitory effect could be induced by elution of chromium by further oxidation of trivalent chromium, which is one of the main components of passive layer, by highly oxidative radiolysis products.